Effect of the structure of titanium–magnesium catalysts on the morphology of polyethylene produced

The structure and formation of polyethylene (PE) particles on supported titanium–magnesium catalysts having different structural characteristics (sizes of microcrystallites, mesopores, and subparticles) were studied for the first time. Scanning electron microscopy was used to identify structural elements of the polymer particles formed over such catalysts and to reveal morphological changes in the growing polymer particles when the yield was increased from approximately 0.2 g PE/g catalyst to approximately 13 kg PE/g catalyst. A relationship was found between structural characteristics of the porous catalyst particles, morphology of the nascent polymer particles, and bulk density of the polymer powder. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2298–2308     

Multiaxial mechanical behavior of aramid fibers and identification of skin/core structure from single fiber transverse compression testing

The transverse and longitudinal mechanical properties of aramid fibers like Kevlar? 29 (K29) fibers are strongly linked to their highly oriented structure. Mechanical characterization at the single fiber scale is challenging especially when the diameter is as small as 15 µm. Longitudinal tensile tests on single K29 fibers and single fiber transverse compression test (SFTCT) have been developed. Our approach consists of coupling morphological observations and mechanical experiments with SFTCT analysis by comparing analytical solutions and finite element modeling. New insights on the analysis of the transverse direction response are highlighted. Systematic loading/unloading compression tests enable to experimentally determine a transverse elastic limit. Taking account of the strong anisotropy of the fiber, the transverse mechanical response sheds light on a skin/core architecture. More importantly, results suggest that the skin of the fiber, typically representing a shell of one micrometer in thickness, has a transverse apparent modulus of 0.2 GPa. That is around more than fifteen times lower than the transverse modulus of 3.0 GPa in the core. By comparison, the measured longitudinal modulus is about 84 GPa. The stress distribution in the fiber is explored and the critical areas for damage initiation are discussed. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 374–384     

A new high frequency dynamic mechanical analysis system: An approach to direct high frequency testing of tire tread rubber

Dynamic Mechanical Analysis (DMA) systems are measurement devices for obtaining master curves and complex modules of viscoelastic materials, such as rubbers. The conventional DMAs measurement systems in market have several limitations, which restrict their ability for operating at high frequencies. Thus, Williams, Landel and Ferry (WLF) relation is used to produce master curves and predict the material properties at high frequencies. In conventional DMAs, experiments are done in a range of temperatures, and then a master curve is made for a chosen reference temperature by shifting the measurements data to high frequencies. Therefore, the obtained results, which are not based on direct measurements, can be inaccurate. In order to overcome this problem a new simple shear high-frequency DMA (HFDMA) system is designed and built to directly measure the dynamic mechanical properties of viscoelastic material at high frequencies and the strain levels sufficient for tire manufacturers. The new HFDMA can be used to test any viscoelastic materials which have glass transmission temperature (Tg) lower than room temperature (about 23 °C) such as the Styrene-butadiene rubber (SBR). The SBR is the base material for tire tread. The designing process of this new HFDMA is presented in this paper. The rubber specimen shape is chosen by taking into account the shear elastic wave effect, bending, buckling effect and heat generation in the specimen. The repeatability test is accomplished to ensure that the results obtained from the new HFDMA are repeatable and the repeatability uncertainty is about 0.04%. The new HFDMA is validated by comparing to the direct test results of conventional DMA at 100 Hz. The direct high frequency (5 kHz) complex shear modulus and damping factor are compared with the master curve of the conventional DMA developed by the use of WLF relation for SBR. This comparison revealed that the complex shear modulus and damping factor of the SBR obtained from the HFDMA at 5 kHz and 0.05% strain amplitude are about 7% and 6.5% higher than those obtained from the conventional DMA, respectively.     

Canonical characteristic relation for two dimensional Euler equations

We propose a new way of rewriting the two dimensional Euler equations and derive an original canonical characteristic relation based on the characteristic theory of hyperbolic systems. This relation contains the derivatives strictly along the bicharacteristic directions, and can be viewed as the 2D extension of the characteristic relation in 1D case.     

ELECTRE: Robust ordinal regression for outranking methods

We present a new method, called ELECTRE^GKMS, which employs robust ordinal regression to construct a set of outranking models compatible with preference information. The preference information supplied by the decision maker (DM) is composed of pairwise comparisons stating the truth or falsity of the outranking relation for some real or fictitious reference alternatives. Moreover, the DM specifies some ranges of variation of comparison thresholds on considered pseudo-criteria. Using robust ordinal regression, the method builds a set of values of concordance indices, concordance thresholds, indifference, preference, and veto thresholds, for which all specified pairwise comparisons can be restored. Such sets are called compatible outranking models. Using these models, two outranking relations are defined, necessary and possible. Whether for an ordered pair of alternatives there is necessary or possible outranking depends on the truth of outranking relation for all or at least one compatible model, respectively. Distinguishing the most certain recommendation worked out by the necessary outranking, and a possible recommendation worked out by the possible outranking, ELECTRE^GKMS answers questions of robustness concern. The method is intended to be used interactively with incremental specification of pairwise comparisons, possibly with decreasing confidence levels. In this way, the necessary and possible outranking relations can be, respectively, enriched or impoverished with the growth of the number of pairwise comparisons. Furthermore, the method is able to identify troublesome pieces of preference information which are responsible for incompatibility. The necessary and possible outranking relations are to be exploited as usual outranking relations to work out recommendation in choice or ranking problems. The introduced approach is illustrated by a didactic example showing how ELECTRE^GKMS can support real-world decision problems.     

复合功能布的动态力学性能及本构关系

针对复合功能布的物理特性,利用材料试验机和分离式Hopkinson压杆装置,展开了准静态和动态条件下单层和双层复合功能布材料的单轴抗压实验,获得了两种材料在不同应变率下的应力应变曲线和材料的失效应力、应变.实验结果表明:复合功能布的动态失效强度明显高于准静态失效强度,而且随着应变率的增加其动态失效强度呈现增加的趋势,即该材料具有明显的应变率硬化效应.对应力应变曲线进行拟合,给出了材料的动静态粘弹性本构关系.并对复合功能布在不同应变率下的失效应变及材料的损伤结果进行了初步的分析.     

7A04铝合金的本构关系和失效模型

使用万能材料试验机、扭转试验机和Taylor撞击实验研究了高强铝合金7A04在常温至250 ℃的 准静态、动态本构关系和失效模型。基于实验结果,修改了Johnson-Cook强度模型中的应变强化项以及 Johnson-Cook失效模型中的温度软化项,并结合数值模拟标定了模型参数。实验结果表明,7A04铝合金的 应变和应变率强化效应不显著,失效应变随温度的增加、应力三轴度的减小和应变率的减小而增加。     

A comparative study of dispersion relation of EM waves in ternary one-dimensional plasma photonic crystals having two different structures

In this paper, a rigorous theoretical analysis has been made to study the dispersion relation of EM waves in periodic ternary one-dimensional photonic crystal having two different structures. In one case we have chosen glass-plasma and ZnS in one unit cell and in other case we have considered glass-plasma and M_gF₂ in one unit cell. Using Kronig-Penney model the dispersion relation for proposed structures has been obtained and numerical results are presented in the form of dispersion curves. The dependence of photonic band gap (PBG) characteristics on plasma frequency, plasma width and the width of dielectric media are discussed in the light of frequency gap and cutoffs of binary one-dimensional plasma photonic crystal. An attempt has been made to show how the PBG characteristic of a particular structure changes when the dielectric materials of its unit cell is changed by the other dielectric material. It is found that the structure having glass-plasma-ZnS in unit cell is more useful for broad band filtering and other plasma functioning devices compared to the structure having glass-plasma-MgF₂ in one unit cell.     

Directional coupler design based on coupled cavity waveguides in photonic crystals

We propose a directional coupler design based on coupled cavity waveguide in photonic crystals. The plane wave expansion is used to give the dispersion of the coupled cavity waveguides and two parallel such waveguides. The couple length is got from the dispersion curves. Based on the research of the dispersion, we present a directional coupler and the transmission property is given. This structure is potentially important for highly efficient directional coupler in integrate optical circuit.     

Superhydrophobicity of silica nanoparticles modified with polystyrene

Polystyrene/silica nanoparticles were prepared by radical polymerization of silica nanoparticles possessing vinyl groups and styrene with benzoyl peroxide. The resulting vinyl silica nanoparticles, polystyrene/silica nanoparticles were characterized by means of Fourier transformation infrared spectroscopy, scanning electron microscopy and UV-vis absorption spectroscopy. The results indicated that polystyrene had been successfully grafted onto vinyl silica nanoparticles via covalent bond. The morphological structure of polystyrene/silica nanoparticles film, investigated by scanning electron microscopy, showed a characteristic rough structure. Surface wetting properties of the polystyrene/silica nanoparticles film were evaluated by measuring water contact angle and the sliding angle using a contact angle goniometer, which were measured to be 159° and 2°, respectively. The excellent superhydrophobic property enlarges potential applications of the superhydrophobic surfaces.